Former Principals
Sree Sankara College, since its inception, has been fortunate to have great visionaries and educationists at its helm as Principals, as listed below.
| 1. | Prof. K. V. Krishna Iyer | 1954-1955 |
| 2. | Prof. V. R. Srinivasaraghavan | 1955-1958 |
| 3. | Prof. B. Anandavally Amma | 1958-1959 |
| 4. | Prof. E. Raman Menon | 1959-1961 |
| 5. | Prof. C. V. Sethunathan | 1961- 1965 |
| 6. | Prof. S. Seetharama Iyer | 1965 |
| 7. | Prof. S. Narayana Iyer | 1965-1966 |
| 8. | Prof. K. S. Rama Iyer | 1966-1968 |
| 9. | Prof. N. S. Venguswami | 1968-1969 |
| 10. | Prof. V. Radhakrishnan | 1969-1970 |
| 11. | Prof. C. K. Sivarama Pillai | 1970-1971 |
| 12. | Prof. S.V. Nayar | 1971-1972 |
| 13. | Prof. A. N. Karunakaran Pillai | 1972-1978 |
| 14. | Prof. C. K. Sivarama Pillai | 1978-1986 |
| 15. | Prof. R. Padmanabhan Potti | 1986-1990 |
| 16. | Prof. S. Subramonia Iyer | 1990-1991 |
| 17. | Prof. R. Kalyanasundaram | 1991-1994 |
| 18. | Prof. V. H. Narayanaswamy | 1994-1996 |
| 19. | Prof. P. S. Ramachandran | 1996-2001 |
| 20. | Prof. A. J. Vishnu | 2001-2002 |
| 21. | Prof. A. Subramonia Iyer | 2002-2003 |
| 22. | Prof. M. J. Ushadevi | 2003-2006 |
| 23. | Dr. K. P. Gopinanathan Nair | 2006-2007 |
| 24. | Capt. Dr. M.K. Ramachandran | 2007-2013 |
| 25. | Dr. V. Rajalakshmi | 2013-2015 |
| 26. | Dr. K.A. Ajith Kumar | 2015-2018 |
| 27. | Sri. Sambhu Nampoothiri N (DDO) | 2018-2019 |
| 28. | Dr. Suresh A | 2019-2022 |
| 29. | Dr. Preethi Nair | 2022 – 2024 |
| 30. | Prof (Dr.) Anilkumar. M | 2024 – |